No approver found for Purchase Requisition XX

I was working on one client site for AME setup with Purchase Requisition. I finished setup for AME transaction Type “Purchase Requisition Approval”. When requester was submitting requisition system initially shows that it’s in process but after one minute requester was getting notification “No approver found for Purchase Requisition”.
I checked from AME Test Workbench functionality by using transaction ID system was generating approval list as per setup. In other words everything was setup properly but still after submission user was getting error while submitting from Core Purchasing Form.

If user was completing this purchase requisition by using iProcurement Checkout functionality request was going for approval to supervisor as per setup.

After 2 days of working, found out one silly problem .guess what????????

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